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Guide to Contaminants and Technologies
The information presented below is intended to help brownfields
stakeholders better understand the types of contaminants typically found
at brownfields sites and the range of technologies that may be appropriate
for assessing and remediating those contaminants during the various phases
of a site cleanup.
- Top -
What Are the Causes of Contamination at Brownfields
Sites?
Section 101 of the Comprehensive
Environmental Response, Compensation, and Liability Act (CERCLA) defines
brownfields sites as “real property, the expansion, redevelopment, or
reuse of which may be complicated by the presence or potential presence
of a hazardous substance, pollutant, or contaminant.” Almost any former
property, industrial or nonindustrial, where chemicals were used, produced,
or reclaimed is a potential brownfields site. Over the operational history
of the site or through its current use, contamination may have resulted
from use, storage, or disposal of various products or chemicals. Some
of the products commonly used or generated at the sites that may have
resulted in contamination of structures, soils, or groundwater include
the following:
- Acids and bases
- Insulation
- Batteries
- Motor oil
- Cleaning products
- Oil sludge and waste oil
- Coal tar
- Paints
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- Degreasing agents
- Pesticides, herbicides, and insecticides
- Diesel fuel
- Plastics
- Dyes, pigments, and inks
- Polymers and epoxy compounds
- Electrical equipment
- Refrigerants and coolants
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- Explosives and ordnance
- Soaps
- Fertilizers
- Solvents
- Gasoline
- Surfactants
- Hydraulic fluids and lubricants
- Waxes
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A wide variety of chemical contaminants may be present at brownfields
sites. The following tables present information on the sites, typical
contaminants, and investigative and remedial technologies:
- Table A-1 lists common site types, activities that may have lead to
contamination, and contaminant groups typically associated with the
site types
- Table A-2 lists technologies used to analyze contaminants commonly
found at brownfields sites
- Table A-3 lists technologies used to treat contaminants commonly found
at brownfields sites
Seven general contaminant groups are included in Tables A-1, A-2, and
A-3. Descriptions of the seven contaminant groups have been included at
the end of this guide to provide supplemental information about them.
In addition, supplemental information about treatment technologies described
in Table A-3 also has been included at the end of this guide.
The information in this guide was obtained from various U.S. Environmental
Protection Agency (EPA) sources. It is intended to provide general information
on brownfields sites, contaminants, and technologies and is not intended
to be all-inclusive. Contaminants and activities associated with common
brownfields site types may not be relevant to every site. Additionally,
investigation and remediation technologies may not be appropriate for
the listed contaminants in all situations. Stakeholders should consult
EPA or state officials, qualified professionals, and other sources of
information when proceeding with redevelopment activities.
- Top -
What Types of Contaminants Are Found at Brownfields
Sites?
Various contaminants potentially may be present at brownfields sites.
Table A-1 lists common brownfields site types, activities that may have
lead to contamination over the operational history of these sites, and
the contaminant groups typically associated with these activities. In
this guide, contaminant groups are presented rather than the specific
contaminants. Information about the contaminant groups is included below
under What Are the Contaminant
Groups Presented in Tables A-1, A-2, and A-3? Please note that if a contaminant
group is listed, it does not imply that all the contaminants within a
particular group are associated with each site type.
- Top -
Table A.1. Typical Contaminants Found at Brownfields
Sites
| Site Type and Activities |
Halogen-ated
VOCs
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Non-halogen-ated
VOCs
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Halogen-ated
SVOCs
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Non-halogen-ated
SVOCs
 |
Fuels
|
Metals
and Metal-loids
 |
Explo-sives
|
 |
Agricultural
Feed supply and other agricultural chemical distribution points may
be contaminated with fertilizers, pesticides, and herbicides. Groundwater,
drainage area sediments, soils, and nearby surface waters may be contaminated
with pesticides and herbicides and could exhibit elevated levels of
nitrate from fertilizer runoff. Contamination at agricultural sites
may also arise from chemicals used to operate, clean, and maintain
farm equipment such as fuel, oil, grease, and solvents. |
x |
x |
x |
x |
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x |
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Battery recycling and disposal
Battery recycling and disposal facilities regenerate, reclaim, and
dispose of used batteries. Many batteries contain toxic constituents
such as lead, mercury, and cadmium. The metal in used batteries is
separated from other battery constituents and processed for reuse.
Lead-acid automobile batteries must be “broken” to reclaim the lead
within. In battery breaking, the top of the battery casing is removed,
the sulfuric acid solution inside is drained, and the lead components
are separated from the casing. The remaining battery casing may be
rinsed prior to disposal in order to remove residual lead oxide. Discarded
acid and rinse water may be stored in lagoons or tanks. Chemicals
may be released to soil and groundwater by leaking tanks or through
spillage during the breaking process. Discarded casings may be buried.
Any metal remaining on buried, discarded casings may leach into soil
and groundwater. The extracted metal must be smelted prior to reuse.
Particulate matter emitted by the smelter may contaminate nearby surface
soil. |
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Chemical and dye manufacturing
A wide range of chemicals are used and generated in facilities that
manufacture, reformulate, and package various chemicals and dyes for
commercial and industrial use. The types of contaminants released
depend on the raw materials, processes, equipment and maintenance
practices used. Environmental contamination resulting from chemical
and dye manufacturing may persist in nearby or downstream surface
waters or sediments long after operations have ceased. Moreover, chemical
operations can change over time or involve multiple processes; therefore,
the sites may be overlaid with several generations of wastes from
a variety of products or processes. Many chemical facilities also
have quality assurance and research laboratories that use small quantities
of toxic chemicals that could contaminate isolated locations. |
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x |
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Chlor-alkali manufacturing
Chlor-alkali plants produce a variety of chemicals, including chlorine,
caustic soda, hydrochloric acid, sodium hypochlorite, sodium hydrosulfite,
salt, hydrogen, sulfur dioxide, and spent sulfuric acid. Three basic
processes are used for the manufacture of chlorine and caustic soda
from brine: the mercury cell, diaphragm cell, and membrane cell processes.
The mercury cell process uses elemental mercury as the cathode and
produces mercury-contaminated wastewater, solid waste, and gaseous
emissions. The process and waste streams must be carefully controlled
to prevent the release of mercury to the environment. The diaphragm
cell process may use lead or graphite anodes and asbestos diaphragms
and may generate chlorinated hydrocarbons as a by-product. The membrane
cell process is the most modern and has economic and environmental
advantages. The primary by-product of the membrane cell process is
dilute hydrochloric acid, which must be neutralized before it is discharged
into the environment. |
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Cosmetics manufacturing
Cosmetics are mixtures of surfactants, oils, and other ingredients.
Cosmetics may contain mineral or metallic and nonmetallic additives.
In sunscreen, for example, titanium and zinc are used as sun blockers.
The color of makeup is determined by the concentrations and ratio
of black or red iron oxide, titanium dioxide, and/or zinc oxide. Metal
dyes are used in fingernail polish. The uses and concentrations of
heavy metals play an important role in cosmetics production and a
primary environmental concern at these site types. |
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Drum recycling
Drum recycling facilities clean used drums for reuse. Soil and groundwater
contamination at these facilities may result from leaking and spilling
of residual chemicals and oils. The variety of chemicals stored in
drums makes characterizing potential contaminants difficult. Contaminants
could include acids, bases, corrosives, reactive chemicals, flammable
materials, and oils. Spillage of paint, paint thinners, and solvents
can also contaminate drum recycling facilities. |
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x |
x |
x |
x |
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Dry cleaning
The dry cleaning industry provides garment cleaning and related services
such as clothes pressing and finishing. The dry cleaning process is
physically very similar to the home laundry process except that clothes
are washed in dry cleaning solvent instead of water. Dry cleaning
sites may become contaminated because of leaks, spills, and improper
disposal of solvents. |
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Gasoline stations
Gasoline stations consist of pump islands, underground storage tanks
(UST) for fuel, small storage areas, and service areas (which typically
contain either hydraulic lifts or pits) for changing automobile engine
oil and other maintenance activities. Gasoline and diesel fuel are
transferred from bulk tank trucks to large USTs. Spills at the transfer
areas and pumps along with overfilling of and leakage from the USTs
are likely sources of contamination at gasoline stations. The primary
contaminants of concern at gasoline stations include petroleum hydrocarbons;
Benzene, Toluene, Ethylbenzene, and Xylenes (BTEX); and fuel oxygenates
such as methyl tertiary butyl ether. Service areas typically have
small containers of ethylene glycol (coolant), hydraulic oils, lubricants,
automotive batteries (lead and acid), and compressed gas especially
acetylene and oxygen cylinders for welding operations. Surface soils
may be contaminated because of historical spills or dumping of used
lubricants, coolants, and cleaning solvents generated during service
activities. Subsurface soils and groundwater, especially in the vicinity
of USTs, may also be contaminated because of spills, overfilling,
and leaks. |
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x |
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Glass manufacturing
The glass industry consists of firms engaged in primary glass manufacturing
and of others that create products using purchased glass. The primary
contaminants associated with glass manufacturing are metals such as
lead, arsenic, chromium, and others. Other chemicals used in the glass
manufacturing process include hydrofluoric acid, sulfuric acid, and
various organic and inorganic solvents. Contaminants may be released
to the environment through spills and leaks of raw materials and plant
maintenance waste as well as insufficiently treated air emissions. |
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Hospitals
Hospitals use a variety of toxic chemicals for diagnostic and therapeutic
procedures as well as for cleaning and sterilization. Hazardous materials
used include chemotherapy and antineoplastic chemicals, formaldehyde,
photographic chemicals, radionuclides, solvents, mercury, anesthetic
gases, and other toxic or corrosive chemicals. These substances may
be released to the environment through leaks and spills, improper
disposal of wastes, and insufficient treatment of wasterwater. In
addition, medical waste incinerators may release mercury into the
air. |
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x |
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Incinerators
An incinerator is an enclosed device that uses controlled flame combustion
to thermally break down waste to an ash residue that contains little
or no combustible material. Incinerators may accept specific wastes
such as municipal solid waste, sewage sludge, or medical waste. Contamination
from incinerators may be associated with storage and handling of waste
materials prior to incineration as well as disposal of ash and other
by-products of the combustion process. |
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Landfills, municipal and industrial
Landfills are now restricted to household garbage, yard wastes, construction
debris, and office wastes. Prior to 1970, however, landfills could
accept industrial wastes. Therefore, older landfills are more likely
to be contaminated with hazardous chemicals. Even modern landfills
can contain a host of chemicals from household wastes such as oils,
paints, solvents, corrosive cleaners, batteries, and gardening products.
Illegal dumping at landfills can also cause serious contamination.
Improperly designed landfills have a higher likelihood of surface
soil and groundwater contamination and may trap explosive levels of
methane gas and hydrogen sulfide in the soil. |
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Leather manufacturing
Leather tanning is the process of converting raw hides or skins into
leather. Hides and skins absorb tannic acid and other chemical substances
that prevent them from decaying, make them resistant to wetting, and
keep them supple and durable. Tanning is essentially the reaction
of collagen fibers in the hide with tannins, chromium, alum, or other
chemical agents. The most common tanning agents used in the United
States are trivalent chromium and vegetable tannins extracted from
certain tree barks. Alum, syntans (manmade chemicals), formaldehyde,
glutaraldehyde, and heavy oils are also used as tanning agents. |
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Machine shops and metal fabrication
The fabricated metal product industry has facilities that generally
perform two functions: forming metal shapes and performing metal finishing
operations, including surface preparation. Metal fabricators produce
ferrous and nonferrous metal products. Machining and other metal working
may generate waste metals, lubricants, cleaners, and other materials.
These substances may impact soil, groundwater, and surface water if
they are spilled, leaked, or improperly disposed. |
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x |
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Manufactured gas plants and coal gasification
Manufactured gas has been produced as a fuel source from coal and
oil since the early 1800s. Typically, coal or oil is heated and the
resulting volatilized gases are distilled to produce natural gas.
Depending on the process design, various by-products can be recovered,
including anthracene, benzene, cresol, naphthalene, paraffin, phenol,
toluene, and xylenes. Waste products from manufactured gas operations
include coal fines, coal tar, cyanide salts, hydrogen sulfide gas,
ammonia, and wastewater. Leakage and spillage from storage drums or
tanks may contaminate surface and subsurface soils, sediments, surface
water, and groundwater. |
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Marine maintenance
Marine maintenance industry establishments engage in general painting
and repair of ship or boat structures and engines or power plants.
Activities may include painting, servicing engines, structural repairs,
engine or power plant maintenance, electroplating, air conditioning
and refrigeration service, electrical repair, and other cleaning and
repair services. A number of chemicals may be used at marine maintenance
facilities, including chemical paint strippers, blast media, antifouling
paints, solvents, carburetor cleaner, cutting fluids, acids and alkalis,
cyanide, heavy metal baths, fiberglass and reinforcement, resins,
and mold release agents. |
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Metal plating and finishing
Metal plating operations improve a product’s performance (for example
its durability or corrosion resistance) or appearance. Metal components
are first cleaned (using solvents and/or water-based detergents) to
remove dirt and oils from manufacturing operations. The metal components
are subsequently etched, plated, and finished in a series of vats
or baths. Common plating metals include cadmium, chromium, copper,
gold, nickel, silver, and their alloys. Spillage during plating and
cleaning operations and leakage or overflows from storage tanks and
process vats may contaminate concrete floors and underlying soils.
Groundwater may also be contaminated by heavy metals, cyanide, and
solvents. |
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x |
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Metal recycling and automobile salvage
Automobile salvage yards recover usable parts, scrap metal, and other
recyclable materials from old or wrecked automobiles. Nonrecyclable
materials are stored on site or sent to a municipal landfill. Metal
recyclers purchase metal from a variety of sources and sort and process
the scrap metal for resale. Metals commonly salvaged by these facilities
include iron, steel, copper, brass, and aluminum. Sites may contain
non-recyclable wastes and contaminated materials. Contaminated “auto
fluff”, a fibrous residue containing plastics, fabrics, and other
materials, may be present at sites that perform shredding. Depending
on the type of recycling operation conducted at a site, the surrounding
soils may be contaminated with heavy metals, asbestos, polychlorinated
biphenyls (PCB) oils, hydraulic fluids, lubricating oils, fuels, and
solvents. |
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Munitions manufacturing and ordnance
sites
Ordnance sites typically include facilities that manufacture, assemble,
store, or dispose of a variety of military munitions such as bombs,
shells, grenades, mines, small arms ammunition, and specialty explosives.
Potential contaminants in structures and surrounding property include
di- and tri-nitro substituted phenols and benzenes, nitroglycerin,
metals, ethers, formaldehyde, and ammoniated compounds. Unexploded
ordnance (UXO) may be buried along with other waste materials. Groundwater
may be contaminated with solvents such as formaldehyde and toluene.
Furthermore, because of the age of some facilities, asbestos-containing
materials may be found in abandoned buildings and demolition debris. |
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Mining
There are three general steps in the mining process: extraction, beneficiation,
and processing. Extraction of the mineral value from the rock or matrix
is the initial step in the operation. Beneficiation is the processing
of extracted materials to clean or concentrate the product either
for use as a final product or in preparation for further processing.
Beneficiation may involve physical (such as milling) or chemical (such
as leaching) separation processes or both. Processing is conducted
following beneficiation to further extract or refine the material
and prepare it for specific uses. Processing may include a variety
of operations such as smelting, refining, roasting and digesting.
Chemical contamination at mining sites may result from acidic, metal-laden
mine drainage. Spilled, leaked, or improperly disposed of petroleum,
lubricants, and other industrial chemicals may also result in site
contamination. |
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Painting and automobile body repair
Paint shops and automobile body repair shops paint various plastic
and metal products and fix truck and automobile body parts. Damaged
automobile body parts are replaced or repaired with fillers and are
then sanded, primed, and painted. The shops may use cutting torches,
welding equipment, solvents and cleaners, fiberglass, various polymers
and epoxy compounds, and sand or grit blasting. Gasoline and diesel
from vehicle fuel tanks, solvents, cleaners, acids, and paints may
be leaked or spilled, contaminating soils and groundwater. Typical
contaminants include toluene, acetone, perchloroethylene, xylene,
gasoline and diesel fuel, carbon tetrachloride, and hydrochloric and
phosphoric acids. |
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Pesticide manufacturing and use
A pesticide is any substance or mixture of substances intended for
preventing, destroying, repelling, or mitigating any pest. The term
pesticide also applies to herbicides, fungicides, and various other
substances used to control pests. Spillage, leakage, and improper
storage or disposal of pesticides may result in their release to the
environment. Sites may also be contaminated with properly applied
but persistent pesticides. Because of the wide variety of pesticides
and applications, facilities manufacturing or using pesticides may
be contaminated with a broad range of chemicals. |
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Petroleum refining and reuse
Oil production facilities consist of oil drilling, refining, storage,
transfer, transport, and recycling facilities. Typical materials present
at these facilities include crude, fuel, and motor oils as well as
waste oils. Production processes at these facilities may contaminate
soils with sludges, acids, and waste oil additives as well as co-contaminants
such as PCBs when spills, leaks or improper disposal practices occur.
In some cases,disposal pits may contain thick tarry sludges with very
high pH values. Groundwater and deeper soil may be contaminated with
metals and lighter oil fractions such as BTEX. |
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Pharmaceutical manufacturing
The pharmaceutical industry manufactures bulk pharmaceutical intermediates
and active ingredients, that are further processed into finished products.
Chemicals used in the manufacturing process vary according to the
desired product and the process type. Equipment must be thoroughly
cleaned between processing operations for different products. VOCs
are used as solvents at various stages of the manufacturing process.
Because of the purity required for products, spent solvent is not
usually reused in pharmaceutical manufacturing. It may be sold for
nonpharmaceutical use or destroyed via incineration. The ten contaminants
most commonly discharged in pharmaceutical wastewater are methanol;
ethanol; acetone; isopropanol; acetic acid; methylene chloride; formic
acid; ammonium hydroxide; N,N-dimethylacetamide and toluene. |
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Photographic film manufacturing and
development
Photographic film is coated with an emulsion containing light-sensitive
silver halide crystals. Once film has been exposed, it must go through
a series of chemical processes to bring out the images. Various chemicals
are used as developers and fixing solutions, including hydroquinone,
catechols, aminophenols, acetic acid, muriatic (hydrochloric) acid,
and sodium or ammonium thiosulfate. Silver solutions are often generated
during the photographic development processes. |
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Plastic manufacturing
Almost all plastics are made from petroleum. Plastics are polymers,
which are very long chains of molecules that consist of subunits (monomers)
linked together by chemical bonds. Monomers of petrochemical plastics
are not typically biodegradable. Wastes generated by the industry
include polymers, phthalates, cadmium, solvents, resins, chemical
additives, and VOCs. |
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Printing and ink manufacturing
The printing industry consists of firms engaged in printing using
one or more common processes such as lithography, letterpress, flexography,
gravure, and screen printing. Contamination may result from spills,
leaks, and improper disposal of excess chemicals and wastes, including
ink constituents such as metals, cleaners, and solvents used during
printing and production processes. |
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Railroad yards
Railroad yards may consist of any combination of track and switching
areas, engine maintenance buildings, engine fueling areas, bulk and
container storage and transfer stations, and storage areas for materials
used in track and engine maintenance. Materials used at railroad yards
include diesel fuel, paint, solvents and degreasing agents, PCB oils,
and creosote. Spills, leaks, or dumping of these compounds may contaminate
soil and groundwater. Chemical spills and leaks during loading and
unloading of tanker and freight cars can also contaminate a railroads
yard. Because of the variety of chemicals used at and transported
through railroad yards, virtually any type of chemical contamination
could be present. |
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Research and educational institutions
Academic institutions are often similar to small cities, as they may
have research laboratories, automobile repair facilities, power plants,
wastewater treatment plants, hazardous waste management and trash
disposal activities, asbestos management activities, drinking water
supply facilities, grounds maintenance activities and incineration
facilities. Educational institutions typically generate small quantities
of a variety of wastes, including inorganic acids, organic solvents,
metals and metal dust, photographic waste, waste oil, paint, heavy
metals, and pesticides. |
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Semiconductor manufacturing
>The semiconductor manufacturing industry is a subset of the electronics
manufacturing industry and produces integrated circuits or “chips.”
Contamination on semiconductor chips is one of the primary reasons
that they fail; therefore, chips are cleaned before and after many
of the manufacturing steps. Chemicals used in the manufacturing process
include various acids, ethylene glycol, hydroxide solutions, halogen
gases, fluorocarbons, chlorine, and various organic solvents. |
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Smelter operations
The primary use of smelting is to produce iron and steel from iron
ore. Smelting is also used to extract copper and other base metals
from raw ores. Contamination from smelting operations often takes
the form of deposition of airborne metals, asbestos, and sulfur compounds
in areas surrounding smelters. Contamination may also result from
improper storage and disposal of raw ores or by-product slag. |
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Underground storage tanks
A UST is a tank and any underground piping connected to a tank where
at least 10 percent of the combined volume is under the ground. USTs
often contain petroleum products, gasoline, or other chemicals. Faulty
installation or inadequate operating and maintenance procedures can
cause USTs to release their contents into the environment. The greatest
potential hazard from leaking USTs is that petroleum fuels, fuel additives,
or other hazardous substances can seep into soil and contaminate groundwater. |
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Vehicle maintenance
Vehicle maintenance involves handling and managing a wide variety
of materials and wastes, including oils, batteries, refrigerants,
antifreeze, solvents, asbestos, and fuels. Improper management and
disposal of wastes as well as leaks from fuel and waste storage containers
may result in contamination of vehicle maintenance facilities. |
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Wood preservation
Wood preservation sites typically consist of wood preparation facilities,
chemical storage tanks, chemical treatment areas (including high-pressure
vessels in many cases), drip or drying areas, and wood storage areas.
Wood is treated with preservative chemicals either by dipping the
wood into a chemical bath or by injecting chemicals into the wood
under pressure. Storage tanks at wood preservation sites could contain
creosote, pentachlorophenol, or chrome-copperarsenate (CCA) solutions
for wood treatment. These chemicals could enter the environment if
the tanks were overfilled or leaked. Contaminated water squeezed from
wood during processing and retort sludge may have spilled on the ground,
causing soil and ground water contamination. As treated wood is transferred
from the treatment area to the drying area, chemicals may drip onto
soil and contaminate the soil and groundwater. Likewise, drippage
in drying areas, especially in older operations where pressure treatment
may not have been used, could result in soil contamination. Runoff
from site could also contaminate nearby surface waters. |
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Wood pulp and paper manufacturing
The pulp and paper industry produces commodity grades of wood pulp,
printing and writing paper, sanitary tissue, industrial-type paper,
containerboard, and boxboard using cellulose fiber from timber or
purchased or recycled fibers. The two steps involved are pulping and
paper or paperboard manufacturing. Pulping is the process of dissolving
wood chips into individual fibers using chemical, semichemical, or
mechanical methods. Pulping is the major source of environmental impacts
in the industry. Chlorinated organic compounds in pulp plant wastewater
sludge are of particular concern because of their tendency to partition
from effluent to solids. Improper treatment or disposal of wastes
may result in contamination being released to the environment. Spills
and leaks of process and waste chemicals are other common sources
of contamination at pulp mills. Air emissions are also problematic
at pulp mills, which are typically noted for their unpleasant odors. |
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Notes:
SVOC = Semivolatile organic compound
VOC = Volatile organic compound
- Top -
What Technologies May Be Used to Investigate
Contamination at Brownfields Sites?
Various analytical technologies may be used to investigate contamination
at brownfields sites. Table A-2 contains information on analytical technologies
that are available for investigating the contaminant groups presented
in Table A-1.
- Top -
Table A-2. Technologies for Analyzing Contaminants
at Brownfields Sites
| |
Halogen-ated VOCs
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Non-halogen-ated VOCs
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Halogen-ated SVOCs
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Non-halogen-ated SVOCs
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Fuels
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Metals and Metal-loids
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Explo-sives
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| Amperometric and Galvanic Cell Sensor |
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| Anodic Stripping Voltammetry |
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| Atomic Absorption Spectroscopy |
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| Catalytic Surface Oxidation |
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x |
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| Chemical Colorimetric Kits |
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x |
x |
x |
x |
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| Chemical Reaction-Based Test Papers |
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| Detector Tubes |
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| Electrochemical Detector Kits |
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| Electromagnetic |
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| Explosimeter |
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| Fiber Optic Chemical Sensors |
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| Field Bioassessment |
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| Flame-Ionization Detector |
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| Fluorescence Spectrophotometry |
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| Fourier Transform Infrared Spectroscopy |
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| Free Product Sensors |
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| Gas Chromatography/ Mass Spectrometry |
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| Ground Penetration Radar |
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| Immunoassay Colorimetric Kits |
x |
x |
x |
x |
x |
x |
x |
| Inductively Coupled Plasma-Atomic Emission Spectroscopy
|
|
|
|
|
|
x |
|
| Infrared Spectroscopy |
x |
x |
x |
x |
x |
|
|
| Ion Chromatography |
|
|
|
|
|
x |
|
| Ion Mobility Spectrometer |
x |
x |
x |
x |
x |
|
x |
| Ion Trap Mass Spectrometry |
x |
x |
x |
x |
|
|
|
| Laser-Induced Breakdown Spectroscopy |
|
|
|
|
|
x |
|
| Laser-Induced Fluorescence/ Cone Penetrometer
|
x |
x |
x |
x |
x |
|
|
| Magnetometry |
|
|
|
|
|
x |
|
| Near Infrared Reflectance/ Transmittance Spectroscopy
|
x |
x |
|
|
|
|
|
| Particle-Induced X-Ray Emissions |
|
|
|
|
|
x |
|
| Photo Ionization Detector |
x |
x |
x |
x |
x |
|
|
| Piezoelectric Sensors |
x |
x |
|
|
|
|
|
| Raman Spectroscopy/ Surface-Enhanced Raman Scattering
(SERS) |
x |
x |
x |
x |
x |
|
|
| Resistivity/ Conductivity |
|
|
|
|
x |
x |
|
| Room-Temperature Phosphorimetry |
|
x |
x |
|
|
|
|
| Scattering/ Absorption LIDAR |
x |
x |
|
|
|
|
|
| Semiconductor Sensors |
x |
x |
|
|
|
|
|
| Soil-Gas Analyzer Systems |
x |
x |
x |
x |
x |
|
x |
| Solid/Porous Fiber Optic |
x |
x |
x |
|
x |
|
|
| Synchronous Luminescence/ Fluorescence |
x |
x |
x |
x |
x |
|
|
| Thin-Layer Chromatography |
|
|
|
x |
|
|
|
| Toxicity Tests |
x |
x |
x |
x |
|
x |
x |
| Titrimetry Kits |
|
|
|
|
x |
|
|
| Ultraviolet Fluorescence |
x |
x |
|
x |
|
|
|
| Ultraviolet Visible Spectrophotometry |
x |
x |
|
x |
x |
|
|
| X-Ray Fluorescence |
x |
|
x |
|
|
x |
x |
| |
 |
 |
 |
 |
 |
 |
 |
- Top -
What Technologies May Be Used to Remediate
at Brownfields Sites?
Various treatment technologies may be used to remediate contamination
at brownfields sites. Table A-3 contains information on treatment technologies
that are available for remediating the contaminants presented in Table
A-1. Descriptions of the remedial technologies are included at the end
of this guide in What Are the
Treatment Technologies Identified in Table A-3?
- Top -
Table A-3. Technologies for Treating Contaminants
Found at Brownfields Sites
| |
Halogen-ated VOCs
 |
Non-halogen-ated VOCs
 |
Halogen-ated SVOCs
 |
Non-halogen-ated SVOCs
 |
Fuels
 |
Metals and Metal-loids
 |
Explo-sives
 |
 |
| Air Sparging |
G |
G |
|
|
G |
|
|
| Bioremediation |
S/G |
S/G |
S/G |
S/G |
S/G |
|
S/G |
| Chemical Treatment |
S/G |
S/G |
S/G |
S/G |
S/G |
S/G |
S/G |
| Electrokinetics |
S/G |
S/G |
S/G |
S/G |
|
S/G |
|
| Flushing |
S/G |
S/G |
S/G |
S/G |
S/G |
S/G |
|
| Incineration |
S |
S |
S |
S |
S |
|
S |
| In-Well Air Stripping |
G |
G |
|
|
|
|
|
| Mechanical Soil Aeration |
S |
|
|
|
|
|
|
| Multi Phase Extraction |
S/G |
S/G |
S/G |
S/G |
S/G |
|
|
| Open Burn/Open Detonation |
|
|
|
|
|
|
S |
| Permeable Reactive Barrier |
G |
G |
G |
G |
G |
G |
G |
| Physical Separation |
|
|
S |
S |
|
S |
|
| Phytoremediation |
S/G |
S/G |
S/G |
S/G |
S/G |
S/G |
S/G |
| Pump and Treat |
G |
G |
G |
G |
G |
G |
G |
| Soil Vapor Extraction |
S |
S |
|
|
S |
|
|
| Soil Washing |
S |
S |
S |
S |
S |
S |
S |
| Solidification/Stabilization |
S |
S |
S |
S |
S |
S |
S |
| Solvent Extraction |
S |
S |
S |
S |
S |
S |
S |
| Thermal Desorption |
S |
S |
S |
S |
S |
|
S |
| Thermal Treatment (in situ) |
S/G |
S/G |
S/G |
S/G |
S/G |
|
|
| Vitrification |
S |
S |
S |
S |
S |
S |
|
| |
 |
 |
 |
 |
 |
 |
 |
Notes:
S and G indicate the media that can be treated using each technology type
S = Soils, sediments, and sludges
G = Groundwater, leachate, and surface water
- Top -
What Are the Contaminant Groups Presented
in Tables A-1, A-2, and A-3?
The following general contaminant groups are included in Tables A-1,
A-2, and A-3:
- Halogenated VOCs
- Nonhalogenated VOCs
- Halogenated SVOCs
- Nonhalogenated SVOCs
- Fuels
- Metals and metalloids
- Explosives
Descriptions of the seven contaminant groups are included below to provide
supplemental information about the characteristics and specific constituents
of the groups.
- Top -
Halogenated VOCs
VOCs are hydrocarbon compounds that evaporate readily at room temperature
A halogenated VOC is a VOC that has a halogen (fluorine, chlorine, bromine,
or iodine) attached to it. Locations where halogenated VOCs may be found
include burn pits, chemical manufacturing plants and disposal areas, contaminated
marine sediments, disposal wells and leach fields, electroplating and
metal finishing shops, firefighting training areas, hangars and aircraft
maintenance areas, landfills and burial pits, leaking storage tanks, radioactive
and mixed waste disposal areas, oxidation ponds and lagoons, dry cleaning
shops, grain storage sites, paint stripping and spray booth areas, pesticide
and herbicide mixing areas, solvent degreasing areas, surface impoundments,
and vehicle maintenance areas. Typical halogenated VOCs encountered at
many sites include those listed below.
| 1-Chloro-2-propene |
Carbon tetrachloride |
Hexachlorobutadiene |
| 1,1-Dichloroethane |
Chlorodibromomethane |
Hexachlorocyclopentadiene |
| 1,1-Dichloroethylene (Vinylidene chloride) |
Chloroethane |
Hexachloroethane |
| 1,1,1-Trichloroethane |
Chloroform |
Monochlorobenzene |
| 1,1,1,2-Tetrachloroethane |
Chloromethane |
Neoprene |
| 1,1,2-Trichloroethane (Vinyl trichloride) |
Chloropropane |
Pentachloroethane |
| 1,1,2,2-Tetrachloroethane (Acetylene tetrachloride)
|
Cis-1,2-dichloroethylene |
Tetrachloroethylene (Perchloroethylene) |
| 1,2-Dichloroethane |
Cis-1,3-dichloropropene |
Trans-1,2-dichloroethylene |
| 1,2-Dichloropropane (Propylene dichloride) |
Dibromochloropropane |
Trans-1,3-dichloropropene |
| 1,2,2-Trifluoroethane (Freon 113) |
Dibromomethane |
Trichloroethylene |
| 2-Butylene dichloride |
Dichloromethane (Methylene chloride) |
Trichlorotrifluoroethane |
| Bromodichloromethane |
Ethylene dibromide |
Vinyl chloride |
| Bromoform |
Fluorotrichloromethane (Freon 11) |
|
| Bromomethane |
Glycerol trichlorohydrin |
|
- Top -
Nonhalogenated VOCs
A nonhalogenated VOC is a VOC that does not have a halogen (fluorine,
chlorine, bromine, or iodine) attached to it. Locations where nonhalogenated
VOCs may be found include burn pits, chemical manufacturing plants and
disposal areas, contaminated marine sediments, disposal wells and leach
fields, electroplating and metal finishing shops, firefighting training
areas, hangars and aircraft maintenance areas, landfills and burial pits,
leaking storage tanks, radioactive and mixed waste disposal areas, oxidation
ponds and lagoons, paint stripping and spray booth areas, pesticide and
herbicide mixing areas, solvent degreasing areas, surface impoundments,
and vehicle maintenance areas. Typical nonhalogenated VOCs (excluding
fuels, BTEX, and gas-phase contaminants) encountered at many sites include
those listed below:
| 1-Butanol (n-Butyl alcohol) |
Carbon disulfide |
Methanol |
| 4-Methyl-2-pentanone (Methyl isobutyl ketone)
|
Cyclohexanone |
Methyl ethyl ketone |
| Acetone |
Ethanol |
Styrene |
| Acrolein |
Ethyl acetate |
Tetrahydrofuran |
| Acrylonitrile |
Ethyl ether |
Vinyl acetate |
| Aminobenzene |
Isobutanol |
|
- Top -
Halogenated SVOCs
SVOCs are hydrocarbon compounds with boiling points greater than 200ºC.
A halogenated SVOC is an SVOC that has a halogen (fluorine, chlorine,
bromine, or iodine) attached to it. Locations where halogenated SVOCs
may be found include burn pits and other combustion sources, chemical
manufacturing plants and disposal areas, contaminated marine sediments,
disposal wells and leach fields, electroplating and metal finishing shops,
firefighting training areas, hangars and aircraft maintenance areas, landfills
and burial pits, leaking storage tanks, radioactive and mixed waste disposal
areas, oxidation ponds and lagoons, dry cleaning shops, grain storage
sites, pesticide and herbicide mixing areas, solvent degreasing areas,
surface impoundments, vehicle maintenance areas and wood preservation
sites. Typical halogenated SVOCs (excluding fuels and explosives) encountered
at many sites include those listed below:
|
1,2-Bis(2-chloroethoxy) ethane
|
3,3-Dichlorobenzidine
|
Chlorobenzilate |
|
1,2-Dichlorobenzene (o-Dichlorobenzene)
|
4-Bromophenyl phenylether
|
Chlorphenothane |
|
1,2,4-Trichlorobenzene
|
4-Chloroaniline
|
Hexachlorobenzene |
|
1,3-Dichlorobenzene (m-Dichlorobenzene)
|
4-Chlorophenyl phenylether
|
Hexachlorobutadiene |
|
1,4-Dichlorobenzene (p-dichlorobenzene)
|
Bis(2-chloroethoxy)ether
|
Hexachlorocyclopentadiene |
|
2-Chloronaphthalene
|
Bis(2-chloroethoxy)methane
|
p-Chloro-m-cresol |
|
2-Chlorophenol
|
Bis(2-chloroethoxy)phthalate
|
Pentachlorobenzene |
|
2,3,7,8-Tetrachlorodibenzo-p-dioxin
|
Bis(2-chloroethyl)ether
|
Pentachlorophenol |
|
2,4-Dichlorophenol
|
Bis(2-chloroisopropyl)ether
|
Polychlorinated biphenyls |
|
2,4,5-Trichlorophenol
|
Chlordane
|
Quintozene |
|
2,4,6-Trichlorophenol
|
Chlorobenzene
|
Tetrachlorophenol |
Pesticides are a subgroup of halogenated SVOCs. Typical pesticides encountered
at many sites include those listed below.
|
Aldrin
|
4,4’-DDD
|
Endosulfan sulfate
|
Heptachlor epoxide |
|
BHC-alpha
|
4,4’-DDE
|
Endrin
|
Malathion |
|
BHC-beta
|
4,4’-DDT
|
Endrin aldehyde
|
Methylparathion |
|
BHC-delta
|
Dieldrin
|
Ethion
|
Parathion |
|
BHC-gamma
|
Endosulfan I
|
Ethyl parathion
|
Toxaphene |
|
Chlordane
|
Endosulfan II
|
Heptachlor
|
|
- Top -
Nonhalogenated SVOCs
A nonhalogenated SVOC is an SVOC that does not have a halogen (fluorine,
chlorine, bromine, or iodine) attached to it. Locations where nonhalogenated
SVOCs may be found include burn pits, chemical manufacturing plants and
disposal areas, contaminated marine sediments, disposal wells and leach
fields, electroplating and metal finishing shops, firefighting training
areas, hangars and aircraft maintenance areas, landfills and burial pits,
leaking storage tanks, radioactive and mixed waste disposal areas, oxidation
ponds and lagoons, pesticide and herbicide mixing areas, solvent degreasing
areas, surface impoundments, and vehicle maintenance areas and wood preservation
sites. Typical nonhalogenated SVOCs (excluding fuels and explosives) encountered
at many sites include those listed below:
|
1-Aminonaphathalene
|
Anthracene
|
Diphenylenemethane (Fluorene) |
|
1,2-Benzacenaphthene
|
Benzidine
|
Ethion |
|
1,2-Diphenylhydrazine
|
Benzo(a)anthracene (Tetraphene)
|
Ethyl parathion |
|
2-Aminonaphthalene
|
Benzo(a)pyrene
|
Indeno(1,2,3-c,d)pyrene |
|
2-Methylnaphthalene
|
Benzo(b)fluoranthene
|
Isophorone |
|
2-Nitroaniline
|
Benzo(k)fluoranthene
|
Malathion |
|
2-Nitrophenol
|
Benzoic acid
|
Methylparathion |
|
2,3-Phenylenepyrene
|
Benzyl alcohol
|
Naphthalene |
|
2,4-Dinitrophenol
|
Bis(2-ethylhexyl)phthalate
|
n-Nitrosodimethylamine |
|
3-Nitroaniline
|
Butyl benzyl phthalate
|
n-Nitrosodi-n-propylamine |
|
4-Nitroaniline
|
Chrysene
|
n-Nitrosodiphenylamine |
|
4-Nitrophenol
|
Dibenzofuran
|
Parathion |
|
4,6-Dinitro-2-methylphenol
|
Diethyl phthalate
|
Phenanthrene |
|
Acenaphthene
|
Dimethyl phthalate
|
| |