Coming Winter 2012

Road Map to Understanding Innovative Technology Options for Brownfields Investigation and Cleanup, 5th Edition
This "back to basics" edition will simplify the road to assessment and cleanup and continue to provide valuable information for stakeholders in or affected by redevelopment of brownfields sites.

For more information, contact Carlos Pachon, EPA Office of Superfund Remediation and Technology Innovation, at pachon.carlos@epa.gov.

U.S. Environmental Protection AgencyBrownfields Road Map

Phytoremediation Technology: A Growing Field

A Quick Look
An aesthetically pleasing, passive cleanup technology powered by solar energy.
A technology that is most useful at sites at which shallow, low levels of contamination are present.
A cost-effective technology that has the potential to clean up a wide variety of brownfields sites.
Can also be used for other functions related to site cleanup, such as erosion control and runoff control.
 

Phytoremediation includes the use of plants and natural processes to remediate or stabilize hazardous wastes in soil, sediments, surface water, or groundwater. By acting as filters or traps, plants can degrade organic pollutants, extract metal contaminants, or contain and stabilize the movement of contaminants. Phytoremediation first was tested actively at waste sites in the early 1990s, and use of the approach has been increasing. Phytoremediation has been implemented on a full or demonstration scale at more than 200 sites nationwide. As the number of projects grows, new information about the cost and performance of phytoremediation will become available.

Phytoremediation provides many advantages because it has the potential to work at a broad variety of sites and on myriad contaminants involving potentially less costs than other options. Types of sites at which phytoremediation has been applied with some degree of success in cleaning up the sites include pipelines, industrial and municipal landfills, agricultural fields, wood treatment sites, military installations, fuel storage tank farms, army ammunition plants, sewage treatment plants, and mining sites.

Phytoremediation is being tested and evaluated for its effectiveness in treating a wide array of contaminants found at brownfields sites. Current results indicate that plants have the potential to enhance remediation of petroleum hydrocarbons, BTEX, polycyclic aromatic hydrocarbons (PAH), PCBs, chlorinated solvents, heavy metals, and pesticide waste. In addition to providing a long-term solution, phytoremediation is an excellent option for providing an interim solution for containing the spread of contaminants and beginning the treatment process. Phytoremediation does not require the excavation of soil, and its application may require only minimal material handling. Further, phytoremediation can have a positive effect on the aesthetic character of a site, may be an attractive alternative for use at large sites at which other methods of remediation are not cost-effective or practical, and can be used in conjunction with other technologies when the redevelopment and land use plans for the site include the use of vegetation.

Decision-makers at brownfields sites at which there are relatively low concentrations of contaminants (that is, organics, nutrients, or metals) over a large cleanup area and in shallow soils, streams, and groundwater should consider the use of phytoremediation. Phytoremediation also may be considered for use in conjunction with other technologies when redevelopment and land use plans for a site include the use of vegetation. Among the types of plants used for phytoremediation are hybrid poplar, willow, and cottonwood trees; rye, Bermuda, sorghum, and fescue grasses; legumes (clover, alfalfa, and cowpeas); aquatic and wetland plants (water hyacinth and bullrush); and hyperaccumulators for metals (such as alpine pennycress for zinc or alyssum for nickel). If levels of contamination are so high that the concentrations of contaminants are toxic to plants (phytotoxic), phytoremediation may not be an effective treatment option.

Because phytoremediation has been used more frequently on a demonstration-scale basis, site owners may find it necessary to show its potential applicability and efficacy on a site-specific basis. Doing so may require an up-front commitment of time and resources to demonstrate that the performance of phytoremediation is comparable to the performance of traditionally accepted technology options. However, such an investment ultimately could save site owners significant amounts of money when they clean up their properties for redevelopment. In recent years, EPA has compiled new information to assist site decision-makers who may be reluctant to use phytotechnology because of the limited amount of information about its use at actual field-scale projects. In a recent paper, Use of Field-Scale Phytotechnology for Chlorinated Solvents, Metals, Explosives and Propellants, and Pesticides STATUS UPDATE (April 2005), EPA provides information on phytotechnology applications and identifies such examples as the Edward Sears property that was used from the mid-1960s to the early 1990s for the repackaging and sale of paints, adhesives, paint thinners, and various military surplus materials. Groundwater at the site was contaminated with a variety of solvents, including methylene chloride, trimethylbenzene, TCE, and xylenes. A field demonstration of phytotechnology using hybrid poplars to clean up shallow groundwater at the site was performed beginning in 1996. Substantial reductions in contaminant concentrations have been reported. For example, data covering the period from 1995 to 2004 shows that concentrations of methylene chloride was reduced from as high as 6,700 ìg/L to below detection; trimethylbenze from as high as 1,890 to 730 ìg/L; and TCE from as high as 510 to 46 ìg/L. Groundwater monitoring is ongoing at the site.

In addition to the document discussed above, other resources are available at www.cluin.org including:

  • Brownfields Technology Primer: Selecting and Using Phytoremediation for Site Cleanup (EPA 542-R-01-006), July 2001
  • Phytoremediation Resource Guide (EPA 542-B-99-003), June 1999

For more information see the following resources:
Assessment of Phytoremediation as an In-Situ Technique for Cleaning Oil-Contaminated Sites
Brownfields Technology Primer: Selecting and Using Phytoremediation for Site Cleanup
EPA 542-R-01-006
Citizen's Guides to Understanding Innovative Treatment Technologies
Activated carbon treatment (EPA 542-F-01-020)
Air stripping (EPA 542-F-01-016)
Bioremediation (EPA 542-F-01-001)
Capping (EPA 542-F-01-022)
Chemical dehalogenation (EPA 542-F-01-010)
Chemical oxidation (EPA 542-F-01-013)
Fracturing (EPA 542-F-01-015)
In situ flushing (EPA 542-F-01-011)
In situ thermal treatment methods (EPA 542-F-01-012)
Incineration (EPA 542-F-01-018)
Monitored natural attenuation (EPA 542-F-01-004)
Permeable reactive barriers (EPA 542-F-01-005)
Phytoremediation (EPA 542-F-01-002)
Pump and treat (EPA 542-F-01-025)
Soil excavation (EPA 542-F-01-023)
Soil vapor extraction (SVE) and air sparging (EPA 542-F-01-006)
Soil washing (EPA 542-F-01-008)
Solidification/stabilization (EPA 542-F-01-024)
Solvent extraction (EPA 542-F-01-009)
Thermal desorption (EPA 542-F-01-003)
Vitrification (EPA 542-F-01-017)
CLU-IN Technology Focus
Evaluation of Phytoremediation for Management of Chlorinated Solvents in Soil and Groundwater
EPA 542-R-05-001
Introduction to Phytoremediation
EPA 600-R-99-107
Overview of the Phytoremediation of Lead and Mercury
Phytoremediation of Contaminated Soil and Ground Water at Hazardous Waste Sites
EPA 540-S-01-005
Phytoremediation Resource Guide
EPA 542-B-99-003
Phytotechnology Technical and Regulatory Guidance (Phyto-2)
The Bioremediation and Phytoremediation of Pesticide-Contaminated Sites

 
Saturday, February 4, 2012

Contents
Background
Introduction
Before You Begin
Site Assessment
Site Investigation
Cleanup Options
Cleanup Design and Implementation
Notice and Acknowledgments
 
Features
Road Map at a Glance
Spotlights on Technologies, Processes, and Initiatives
Guide to Contaminants and Technologies
 
Contacts
State Brownfields Contacts
EPA Regional Brownfields Contacts
EPA Technical Support Contacts
 
Comments and Copies
How to Submit Comments
How to Order Documents
How to Obtain Printed Versions of the Road Map